IODOSOBENZENE

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What is the IODOSOBENZENE ?

IODOSOBENZENE is , while it's Molecular Formula is C6H5 I O. lodosobenzene is a relatively new, selective oxidizing agent which is particularly useful for the preparation of sulfoxides from unsaturated or otherwise sensitive sulfides. The preparation of diallyl, di-2-hydroxyethyl and phenyl 2-chloroethyl sulfoxides illustrates its use.Iodosobenzene diacetate behaves similarly and oxidizes diphenyl and 4-nitro-phenyl 4'-carboxyphenyl sulfide exclusively to the sulfoxides. This reagent failed, however, to oxidize bis(2-nitro-4-trifuoromethylphenyl) sulfide and in the case of bis(2-aminophenyl) sulfide it gave complex products. Iodosobenzene diacetate caused diacetoxylation of the heterocycle of 2,5-diphenyl-1 ,4-dithiadiene rather than oxidation of the sulfide function, and with 2,5-diphenylI-1 ,4-dithiadiene-1-oxide unexpected results were obtained, as discussed in section C-4.Organic Sulfur Compounds

What is the CAS number for IODOSOBENZENE ?

The CAS number of IODOSOBENZENE is 536-80-1.

More information of IODOSOBENZENE 536-80-1 are:

What is IODOSOBENZENE (536-80-1) used for?

Iodosobenzene, also known as C6H5IO, is an amorphous yellow substance that explodes at 210℃ and decomposes with the evolution of iodine vapor. It dissolves in hot water and alcohol and is a basic oxide of a diatomic metal. Iodosobenzene is one of the very first oxidants and remains in use due to its excellent oxygen-transfer behavior and mechanistic cleanliness.

InChI:InChI=1/C6H5IO/c8-7-6-4-2-1-3-5-6/h1-5H

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